Carbonate Petrography

Carbonate petrography is the study of limestones, dolomites and associated deposits under optical or electron microscopes greatly enhances field studies or core observations and can provide a frame of reference for geochemical studies.

25 strangest Geologic Formations on Earth

The strangest formations on Earth.

What causes Earthquake?

Of these various reasons, faulting related to plate movements is by far the most significant. In other words, most earthquakes are due to slip on faults.

The Geologic Column

As stated earlier, no one locality on Earth provides a complete record of our planet’s history, because stratigraphic columns can contain unconformities. But by correlating rocks from locality to locality at millions of places around the world, geologists have pieced together a composite stratigraphic column, called the geologic column, that represents the entirety of Earth history.

Folds and Foliations

Geometry of Folds Imagine a carpet lying flat on the floor. Push on one end of the carpet, and it will wrinkle or contort into a series of wavelike curves. Stresses developed during mountain building can similarly warp or bend bedding and foliation (or other planar features) in rock. The result a curve in the shape of a rock layer is called a fold.

Geometric description of folds

Folds Geometry

It is fascinating to watch folds form and develop in the laboratory, and we can learn much about folds and folding by performing controlled physical experiments and numerical simulations. However, modelling must always be rooted in observations of naturally folded rocks, so geometric analysis of folds formed in different settings and rock types is fundamental. Geometric analysis is important not only in order to understand how various types of folds form, but also when considering such things as hydrocarbon traps and folded ores in the subsurface. There is a wealth of descriptive expressions in use, because folds come in all shapes and sizes. Hence we will start this chapter by going through the basic jargon related to folds and fold geometry.

Shape and orientation 


Folds are best studied in sections perpendicular to the folded layering, or perpendicular to what is defined as the axial surface. In general, folds are made up of a hinge that connects two usually differently oriented limbs. The hinge may be sharp and abrupt, but more commonly the curvature of the hinge is gradual, and a hinge zone is defined. A spectrum of hinge shapes exists, from the pointed hinges of kink bands and chevron folds (sharp and angular folds) to the well-rounded hinges of concentric folds. Classification of folds relative to hinge curvature is referred to as bluntness. The shape of folds can also be compared to mathematical functions, in which case we can apply terms such as amplitude and wavelength. Folds do not necessarily show the regularity of mathematical functions as we know them from classes of elementary algebra. Nevertheless, simple harmonic analysis (Fourier transformation) has been applied in the description of fold shape, where a mathematical function is fitted to a given folded surface.
In multi-layered rocks, folds may be repeated with similar shape in the direction of the axial trace. Such folds are called harmonic. If the folds differ in wavelength and shape along the axial trace or die out in this direction they are said to be disharmonic. The point of maximum curvature of a folded layer is located in the centre of the hinge zone and is called the hinge point. Hinge points are connected in three dimensions by a hinge line. The hinge line is commonly found to be curved, but where it appears as a straight line it is called the fold axis


This takes us to an important element of fold geometry called cylindricity. Folds with straight hinge lines are cylindrical. A cylindrical fold can be viewed as a partly unwrapped cylinder where the axis of the cylinder defines the fold axis. At some scale all folds are non-cylindrical, since they have to start and end somewhere, or transfer strain to neighbouring folds, but the degree of cylindricity varies from fold to fold. Hence, a portion of a fold may appear cylindrical as observed at outcrop, even though some curvature of the axis must exist on a larger scale. Cylindricity has important implications that can be taken advantage of. The most important one is that the poles to a cylindrically folded layer define a great circle, and the pole (p-axis) to that great circle defines the fold axis. When great circles are plotted instead of poles, the great circles to a cylindrically folded layer will cross at a common point representing the fold axis, in this case referred to as the b-axis. This method can be very useful when mapping folded layers in the field, but it also works for other cylindrical structures, such as corrugated fault surfaces. Another convenient property of cylindrical folds is that they can be projected linearly, for example from the surface to a profile. Cylindricity is therefore commonly assumed when projecting mapped structures in an area onto cross-sections, particularly in the early 1900 mapping of the Alps by Swiss geologists such as Emile Argand and Albert Heim. Since the validity of such projections relies on the actual cylindricity of the projected structures, the uncertainty increases with projection distance. 
The axial surface, or axial plane when approximately planar, connects the hinge lines of two or more folded surfaces. The axial trace of a fold is the line of intersection of the axial surface with the surface of observation, typically the surface of an outcrop or a geologic section. The axial trace connects hinge points on this surface. Note that the axial surface does not necessarily bisect the limbs. It is also possible to have two sets of axial surfaces developed, which is the case with so-called box folds, which are also called conjugate folds from the characteristic conjugate sets of axial surfaces. In other cases, folds show axial surfaces with variable orientations, and such folds are called polyclinal. The orientation of a fold is described by the orientation of its axial surface and hinge line. These two parameters can be plotted against each other, and names have been assigned to different fold orientations. Commonly used terms are upright folds (vertical axial plane and horizontal hinge line) and recumbent folds (horizontal axial plane and hinge line). 


An antiform is a structure where the limbs dip down and away from the hinge zone, whereas a synform is the opposite, trough-like shape. Where a stratigraphy is given, an antiform is called an anticline where the rock layers get younger away from the axial surface of the fold. Similarly, a syncline is a trough-shaped fold where layers get younger toward the axial surface. We can even have recumbent synclines and anticlines, because their definitions are related to stratigraphy and youngish direction. However, the terms recumbent and vertical antiforms and synforms have no meaning. 


Imagine a tight to isoclinal recumbent fold being refolded during a later tectonic phase. We now have a set of secondary synforms and antiforms. The younging direction across their respective axial surfaces will depend on whether we are on the inverted or upright limb of the recumbent fold. We now need two new terms, synformal anticline and antiformal syncline, to separate the two cases. A synformal anticline is an anticline because the strata get younger away from its axial surface. At the same time, it has the shape of a synform, i.e. it is synformal. Similarly, an antiformal syncline is a syncline because of the stratigraphic younging direction, but it has the shape of an antiform. Technically, a synformal anticline is the same as an anticline turned upside down, and an antiformal syncline looks like an inverted syncline. 
Remember that these terms only apply when mapping in polyfolded stratigraphic layers, typically in orogenic belts. As already stated, most folds are non-cylindrical to some extent. A non-cylindrical upright antiform is sometimes said to be doubly plunging. Large doubly plunging antiforms can form attractive traps of oil and gas - in fact they form some of the world’s largest hydrocarbon traps. When the non-cylindricity is pronounced, the antiform turns into a dome, which is similar to a cereal bowl turned upside-down. Domes are classic hydrocarbon traps, for example above salt structures, and geoscientists commonly talk about such traps as having a four-way dip closure. Correspondingly, a strongly non-cylindrical synform is in fold terminology called a basin (the cereal bowl right-way up). A monoclinal fold is a sub-cylindrical fold with only one inclined limb. Monoclinal folds (or just monoclines for short) are commonly found as map-scale structures related to reactivation of, or differential compaction across, underlying faults or salt structures. In addition to orientation and stratigraphic relations, folds are commonly described or classified according to tightness. Tightness is characterized by the opening or interlimb angle, which is the angle enclosed by its two limbs. Based on this angle, folds are separated into gentle, open, tight and isoclinal. Tightness generally reflects the amount of strain involved during the folding. Folds usually come in groups or systems, and although folds may be quite non-systematic, neighboring folds tend to show a common style, especially where they occur in rows or trains. In these cases they can, akin to mathematical functions, be described in terms of wavelength, amplitude, inflection point and a reference surface called the enveloping surface. The enveloping surface is the surface tangent to individual hinges along a folded layer.



Dip isogons 


Some folds have layers that maintain their thickness through the fold, while others show thickened limbs or hinges. By orienting the fold so that its axial trace becomes vertical, lines or dip isogons can be drawn between points of equal dip on the outer and inner boundaries of a folded layer. Dip isogons portray the difference between the two boundaries and thus the changes in layer thickness. Based on dip isogons, folds can be classified into the three main types: 
  • Class 1: Dip isogons converge toward the inner arc, which is tighter than the outer arc. 
  • Class 2 (similar folds, also called shear folds): Dip isogons parallel the axial trace. The shapes of the inner and outer arcs are identical. 
  • Class 3: Dip isogons diverge toward the inner arc, which is more open than the outer arc. 
Class 1 folds are further subdivided into classes 1A, 1B and 1C. 1A folds are characterized by thinned hinge zones, while 1B folds, also called parallel folds and, if circle shaped, concentric folds, have constant layer thickness. Class 1C folds have slightly thinned limbs. Class 2 and, particularly, Class 3 folds have even thinner limbs and more thickened hinges. Among these classes, Class 1B (parallel) and 2 (similar) geometries stand out because they are easy to construct and easy to identify in the field. One way of plotting folds according to the dip isogon classification, where folds are considered as upright structures (vertical axial planes), so that the dip of the limb (a) increases in each direction from 0 at the hinge point. This is the thickness measured orthogonal to the layer at one of the two corresponding points of equal dip on each arc.

Symmetry and order 

Folds can be symmetric or asymmetric in cross-section. A fold is perfectly symmetric if, when looking at a cross section perpendicular to the axial surface, the two sides of the axial trace are mirror images of one another. This implies that the two limbs are of equal length. The chevron folds and concentric folds are examples of symmetric folds. If we extend this concept to three dimensions, the axial plane becomes a mirror plane, and the most symmetric folds that we can think of have two other mirror planes perpendicular to the axial plane. This is the requirement of orthorhombic symmetry. For symmetric folds the bisecting surface coincides with the axial plane. In fact, this is how we distinguish between kink bands and chevron folds: chevron folds are symmetric while kink bands have one long and one short limb. This leaves us with one symmetry (mirror) plane only, the one perpendicular to the axial surface, and the symmetry is said to be monoclinic


Symmetric folds are sometimes called M-folds, while asymmetric folds are referred to as S-folds and Z-folds. Distinguishing between S- and Z-folds may be confusing to some of us, but Z-folds have short limbs that appear to have been rotated clockwise with respect to their long limbs. Z-folds thus mimic the letter Z when considering the short limb and its two adjacent long limbs. S-folds imply a counter-clockwise rotation, and resemble the letter S (this has nothing to do with the difference in angularity between S and Z). Interestingly, S-folds become Z-folds when viewed from the opposite direction. Plunging folds are usually evaluated when looking down-plunge, while viewing direction must be specified for folds with horizontal axes. 
Fold systems consisting of folds with a consistent asymmetry are said to have a vergence. The vergence can be specified, and the vergence direction is given by the sense of displacement of the upper limb relative to the lower one. We can also relate it to the clockwise rotation of the inclined short limb,where a clockwise rotation implies a right-directed vergence. Fold vergence is important in structural analysis in several ways. Large folds tend to have smaller folds occurring in their limbs and hinge zones. The largest folds are called the first-order folds, while smaller associated folds are second and higher order folds. The latter are also called parasitic folds. First-order folds can be of any size, but where they are map scale we are likely to observe only second- or higher-order folds in outcrops. If a fold system represents parasitic (second order) folds on a first-order synformal or antiformal structure, then their asymmetry or vergence indicates their position on the large-scale structure.This relationship between parasitic and lower order folds can be extremely useful for mapping out fold structures that are too large to be observed in individual outcrops. The vergence of asymmetric fold trains in shear zones is generally unrelated to lower-order folds and can give information about the sense of shear of the zone. Such kinematic analysis requires that the section of observation contains the shear vector and should be used together with independent kinematic indicators.

Fold asymmetry may relate to position on a lower-order fold, sense of shear or orientation of the folded layer relative to the strain ellipse.
Credits: Haakon Fossen (Structural Geology)

Deformation mechanisms and microstructures


When strain accumulates in a deforming rock, certain deformation processes occur at the micro-scale that allow the rock to change its internal structure, shape or volume. The processes involved may vary and in the plastic regime there are other and different processes. If these micro-scale processes lead to a change in shape or volume of a rock we call them deformation mechanisms:
Most of the structures that reveal the type of mechanism at work are microscopic, and we therefore call them micro-structures. They range in size from the atomic scale to the scale of grain aggregates. Intra-crystalline deformation occurs within individual mineral grains. The smallest deformation structures of this kind actually occur on the atomic scale and can only be studied with the aid of the electron microscope. Larger-scale intra-crystalline micro-structures can be studied under the optical microscope, and encompass features such as grain fracturing, deformation twinning and (plastic) deformation bands. When deformation mechanisms produce micro-structures that affect more than one grain, such as grain boundary sliding or fracturing of mineral aggregates, we have inter-crystalline deformation. Inter-crystalline deformation is particularly common during brittle deformation. The two expressions deformation mechanisms and deformation processes are closely related and are often used interchangeably. However, it is sometimes useful to distinguish between the two. Some define deformation mechanisms as processes that lead to strain. There are other microscopic changes that can occur that do not lead to strain, even though they may still be related to deformation. These are still deformation processes, and include rotation recrystallization, grain boundary migration (explained later in this chapter) and, in some cases, rigid rotation. Furthermore, two or more processes can combine to form a (composite) deformation mechanism. Note that the term deformation process is also used in a more general sense in other fields of structural geology.

Strain is accommodated through the activation of one or more micro-scale deformation mechanisms.

Brittle versus plastic deformation mechanisms

Brittle mechanisms dominate the upper crust while plastic mechanisms are increasingly common as pressure and, particularly, temperature increase with depth. However, brittle mechanisms can occur in deep parts of the lithosphere, and plastic mechanisms do occur at or near the surface in some cases. The reason is that not only temperature and pressure control deformation mechanisms, but also the rheology of the deforming mineral(s), availability of fluids and strain rate. While brittle deformation mechanisms can completely dominate deformation of a granitic rock in the upper crust, the transition from completely brittle to perfectly crystal-plastic deformation is gradual. There is a wide range in physical conditions or crustal depths where brittle and plastic mechanisms coexist. For a granitic rock, for example, quartz and feldspar respond differently to stress, particularly for the 300-500 C window. Because most rocks consist of more than one mineral, and different minerals have different brittle-plastic transition windows, the brittle-plastic transition may be a kilometre-thick transition zone even for a single rock type. We therefore find that brittle and plastic deformation mechanisms commonly coexist in the same sample even when deformed at a constant depth during a single phase of deformation.

The controlling deformation mechanism determines whether the deformation belongs to the brittle or plastic regime.

Brittle deformation in an overall plastic setting is mostly restricted to inter-granular fracturing. This is again related to the different ways different minerals respond to stress. Fracturing of a stiff mineral, such as garnet or feldspar,in a matrix of quartz is a typical example. The fractures are restricted to the garnet or feldspar grains, while plastic deformation mechanisms make quartz flow plastically.

Brittle deformation mechanisms


The characteristic feature of brittle deformation is fracturing and frictional sliding. A distinction is drawn between inter-granular fracturing, intra-granular fracturing, frictional sliding on fractures and grain boundaries, and grain rotation. The combination of these deformation mechanisms is called cataclastic flow. Note that intra-granular and intra-crystalline are equivalent expressions, except that intra-granular is used for granular media such as sand and sandstone, while intra-crystalline is used about crystalline rocks where the porosity is (almost) zero. The deformation mechanisms at very shallow depths are different for porous sediments and (almost) non-porous, crystalline rocks. Deformation of an unconsolidated sand or weakly consolidated sandstone buried at less than 1 km depth is governed by two mechanisms: grain rolling (grain rotation) and frictional grain boundary sliding. The process involving these mechanisms is referred to by either of the equivalent terms particulate flow and granular flow. This is inter-granular deformation in the sense that there is no permanent internal deformation of the grains. Granular flow characterizes the deformation of highly porous sediments deforming in a shearing mode or in response to vertical loading (compaction). This is explored in a field of research known as soil mechanics, relevant to slope stability issues and other soil-oriented engineering problems. If the stresses across grain contacts become high enough, grains in a highly porous sediment or sedimentary rock will fracture. The fractures are confined to individual grains and are therefore intra-granular micro-fractures. Under certain circumstances (low pore pressure and small grain contact areas) micro-fractures may form close to the surface, commonly by chipping off small flakes of the grains. This type of micro-fracturing is referred to as spalling or flaking. At higher confining pressures, corresponding to depths in excess of 1 km, fractures split the grains into more evenly sized parts, and this mechanism is sometimes described as trans-granular fracturing. Some use the term trans-granular as a substitute for inter-granular, i.e. about fractures that cut across several grains, so some care should be exercised when using these terms. Once fractured, the grains reorganize themselves by frictional sliding and rotation, leading to porosity reduction. Grains in non-porous or low-porosity rocks develop fractures that may already be inter-granular at the initial stages of deformation. As more and more fractures form, frictional sliding along these fractures together with rotation of grains may be widespread enough that we can characterize the deformation by the term cataclastic flow. From this point on the rock becomes crushed into a gouge, breccia or cataclasite. In general, cataclasis in low-porosity rocks involves dilation and increased permeability as fractures form and open. Incohesive gouge and breccia dominate the uppermost few kilometres of the crust, while cohesive breccia and cataclasite are more common from roughly 3-5 to 10-12 km depth. In the rest of this chapter we will look at crystal-plastic deformation mechanisms.

Growth of fault populations


Faults grow from micro-fractures or deformation band zones and accumulate displacement over time as deformation proceeds. Moreover, faults tend to nucleate at many different places as a region is critically stressed, for instance during rifting, and we refer to such groups of faults as fault populations. In general, many faults in a population soon become inactive and thus remain small. Others reach an intermediate stage before dying, while a few grow into long faults with large displacements. Hence, a fault population is always dominated by small faults, while additional long faults develop as strain accumulates. Faults are unlikely to grow as individual structures over a long period of time. As they grow, they are likely to interfere with nearby faults. In this way two faults can join to form a single and much longer fault. Growth by linkage is a very common mechanism that creates some of the most interesting and important structures in faulted regions.

Fault linkage and relay structures 


In a population where faults grow in length and height, faults and their surrounding stress and strain fields will locally interfere. Let us consider two faults whose tips approach each other during growth. Before the tips have reached each other (but after their strain fields have started to interfere) the faults are said to under lap. Once the tips have passed each other, the faults are overlapping. Under and overlapping faults are said to be soft linked as long as they are not in direct physical contact. Eventually the faults may link up to form a hard link. Under lapping faults “feel” the presence of a neighbouring fault tip in the sense that the energy required to keep the deformation going increases. The propagation rate of the fault tips in the area of under lap is thus reduced, which causes the local displacement gradient to increase. This results in asymmetric displacement profiles, where the maximum is shifted toward the overlapping tip. This asymmetric displacement distribution becomes more pronounced as the faults overlap and the layers in the overlap zone become folded. The folding is a result of ductile displacement transfer (relay) from one fault to the other and is directly related to the high displacement gradients in the overlapping tip zones. If the fault interference occurs perpendicular to the slip direction, which for normal and reverse faults means in the horizontal direction, and if the layering is subhorizontal, then the folding is well expressed in the form of a ramp-like fold. The fold itself is called a relay ramp and the entire structure is known as a relay structure. The ramp is a fold that may contain extension fractures, shear fractures, deformation bands and/or minor faults depending on the mechanical rock properties at the time of deformation. Eventually the ramp will break to form a breached relay ramp. The two faults are then directly connected and associated with an abnormally wide damage zone. Upon breaching there will be a displacement minimum at the location of the relay structure. The total displacement curve along the fault will therefore show two maxima, one on each side of the relay structure. As the deformation proceeds and the fault accumulates displacement, the displacement profile will approach that of a single fault, with a single, central maximum. However, the link is still characterized by the wide damage zone and a step in the horizontal fault trace. If the mapping is based on poorly constrained outcrop information or seismic data (which always have a resolution issue), a sudden change in strike may be the only indication of a breached ramp. Such steps, seen at many locations in the seismic interpretation, are therefore very important as they may hint at the locations of both breached and intact relay ramps. Bends and jogs of faults in map view are very common on many scales. The final fault geometry can be seen to be the result of interaction between individual fault segments through the creation and breaching of relay ramps. The curved fault pattern seen in map view is very similar to that displayed by much larger faults, such as the northern North Sea faults and the Wasatch Fault in Utah, so it seems likely that these large faults formed by fault linkage. Assuming that this analogy holds, we are now able to interpret a deformation history from the geometry of a dead fault system. It is clear that ramps come in any size and stage of development. It is also important to understand that relay ramps and overlap zones are formed and destroyed continuously during the growth of a fault population.

Fault growth by linkage involves the formation and destruction of relay structures, deviations from the ideal elliptical displacement distribution and generation of wide damage zones and fault bends at locations of linkage.

Relay ramp formed between two overlapping fault segments in Arches National Park, Utah.
Fault linkage in the slip direction 

Faults grow in the directions both normal and parallel to the slip direction and therefore interfere in both the vertical and horizontal directions. In the previous section we looked at the horizontal interaction of normal fault tips. Now we will look at the interference of normal fault tips in the vertical plane, i.e. parallel to the slip vector. Fault linkage is most commonly recognized and described in map view, but this is simply because they are easier to observe in map view. Tall vertical sections are less common than long horizontal exposures, and the continuity of good seismic reflectors in the horizontal direction makes it easier to map relays in map view than in the vertical direction. It takes a whole package of good reflectors to identify and map vertical overlap zones on seismic sections. There is therefore a good chance that vertical relay zones are under represented in seismic interpretations. Faults initiate after a certain amount of strain that depends on the mechanical properties (Young’s modulus, etc.). As strong rock layers start to fracture, weak rocks continue to accumulate elastic and ductile deformation. As these fractures grow into faults, they will interfere and connect. In many cases sandstones become faulted before shales. The process is similar to that occurring in map view, except that the angle between the displacement vector and the layering is different. The rotation depends on fault geometry and how the faults interfere. Restraining overlap zones are, in this connection, overlap zones with shortening in the displacement direction. In principle, volume reduction may accommodate the deformation within the zone. More commonly, however, the layers within the overlap zone rotate. Releasing overlap zones are zones where the fault arrangement and sense of displacement cause stretching within the overlap zone. Weak layers such as shale or clay layers are rotated within releasing overlap zones. If the overlap zone is narrow, such weak layers can be smeared along the fault zone. Field observations show that this is a common mechanism for the formation of clay smear in sedimentary sequences, but usually on too small a scale to be detected from seismic data. Such structures may cause faults to be sealing with respect to fluid flow, which can have important implications in petroleum or groundwater reservoirs.

The role of lithology 

Layering or mechanical stratigraphy is important as fault populations develop in layered rocks. The timing of fault formation in the different layers is one aspect, and the way that faults form (ordinary fracturing versus faulting of deformation band zones) is another. Mechanical stratigraphy simply implies that the rock consists of layers that respond mechanically differently to stress, i.e. they have different strengths and different Young’s moduli (E). In simple terms, some layers, such as clay or shale, can accommodate a considerable amount of ductile strain, while other layers, such as limestone or cemented sandstone, fracture at much lower amounts of strain. The result is that, in a layered sequence, fractures or deformation bands initiate in certain layers, while adjacent layers are unaffected or less affected by such brittle structures. So long as the deformation band or fracture grows within a homogeneous layer, a proportionality exists between maximum displacement, length and height. Once the fracture touches the layer boundaries it is called a vertically constrained fracture, and the fracture will only expand in the horizontal direction. This means that the fracture gets longer and longer while its height remains constant, i.e. its eccentricity increases. In fact, its shape is likely to become more rectangular than elliptical.
The moment a fracture is constrained, its area increases only by layer-parallel growth, and its displacement/ length (D/L) ratio becomes lower than what it was during its unconstrained growth history. In simple terms, this is because displacement scales with fracture area, and since the fracture area only increases along its length, the length has to increase at a faster rate relative to displacement. Eventually, if the fracture keeps accumulating displacement, it will break through the bounding interface and expand into the overlying/underlying layers. The D-L relationship will then return to its original trend. The same development is seen for deformation bands in sandstone-shale sequences. At a critical point the deformation band cluster in the sandstone is cut by a slip surface (fault) that extends into the over and/or underlying shale.

The birth and growth of fault

The Birth and growth of fault



Fault formation and growth is a complicated process involving a frontal process zone where micro-fractures form and eventually connect.

Fault formation in non-porous rocks 

Faults in rocks with low or no porosity somehow grow from small shear fractures. However, this cannot happen directly from a single shear fracture, since shear fractures cannot expand in their own planes. Instead they will curve and form wing cracks or related cracks across which there is tension. Experiments show that a phase of intense micro-fracturing occurs prior to fracture initiation or propagation. Once the density of micro-fractures reaches a critical level, the main fracture expands by linkage of favourably oriented micro-fractures. The zone of micro-fractures (and meso-fractures) ahead of the fracture tip zone is called the frictional breakdown zone or the process zone. For a fault to develop, a number of small shear fractures, tensile fractures and hybrid fractures must form and connect. The incipient fault surface is irregular, leading to grinding and micro-fracturing of the walls. A thin core of brecciated or crushed rock typically forms. During fault growth, new fractures form in the walls next to the fault core. Hence, most faults have a well-defined core of intense cataclastic deformation and a surrounding damage zone of less intense fracturing.
Natural rocks are not isotropic, and in many cases faults form along pre-existing mesoscopic weaknesses in the rock. Such weaknesses can be layer interfaces or dikes, but the structures that are most likely to be activated as faults are joints (and, of course, pre-existing faults). Joints tend to be very weak planar structures with little or no cohesion. Joints may also form surfaces many tens of meters or more in length and/or height, because as extension structures they have had the freedom to expand in their own plane. Faults formed by faulting of joints inherit some of the features of the original joints. If a fault forms by frictional sliding on a single, extensive joint, the initial fault tends to be a sharp slip surface with almost no fault core and with (almost) no damage zone. If slip accumulates, however, the fault outgrows the joint and links with other joints in the vicinity of its tip zone. The damage zone then thickens, and the fault core may grow.

Fault formation by joint reactivation requires less stress, causes less off-fault damage (narrower damage zone) and may result in a lower displacement gradient along the fault.

Fault formation in porous rocks 

In highly porous rocks and sediments, fault growth follows a somewhat different path. Pore space gives the grains a unique opportunity to reorganize. If the grains in a sandstone are weakly cemented together, then the grains will reorganize by rotation and frictional grain boundary sliding (translation) during deformation. In other cases grains can also break internally. In either case, the deformation is likely to localize into narrow zones or bands to form structures known as deformation bands. Field observations, as well as experimental and numerical work, show that deformation proceeds by sequential formation of new deformation bands adjacent to the initial one. This means that at some point it becomes easier to form a new band next to the existing one than to keep shearing the primary band. The result is a deformation band zone, and this development is commonly explained in terms of strain hardening. Strain hardening is thought to be related to the loss of porosity in the band and is most pronounced where grains are crushed (cataclastic bands). Note the difference between process zones in non-porous and highly porous rocks: The process zone in non-porous rocks weakens the host rock and increases porosity by the formation of cracks. In high porosity rocks the deformation bands in the process zone in many cases harden the rock and reduce porosity. Once a certain number of deformation bands have accumulated in the deformation band zone, porosity is sufficiently reduced that a slip surface can form and grow. Slip surfaces nucleate in small patches that propagate, link up, and ultimately form through-going slip surfaces. Mechanically, slip surfaces are weak structures that relatively quickly can accumulate meters of slip or more. Through-going slip surfaces are commonly associated with a thin (millimeter-thick) zone of ultracataclasite, which may be considered as the local fault core.

Faults in highly porous rocks form in precursory deformation band zones.

The damage zone 


The growth of deformation bands and/or ordinary fractures prior to the formation of a through-going slip surface has implications for our understanding of the damage zone. The moment the slip surface (fault) forms, the enclosing zone of already existing structures will become the damage zone. Once the fault is established, the process zone in front of the fault tip moves ahead of the fault tip as the fault expands, leaving behind a zone that becomes the initial fault damage zone. In a porous rock, this zone is likely to consist of deformation bands. Because faults form in porous rocks by faulting of a deformation band zone, the length of the deformation band process zone tends to be longer than the process zone seen in many non-porous rocks. This is particularly true if the deformation bands are cataclastic, in which case the process zone can be several hundred meters long. If the structures of the damage zone form ahead of a propagating fault tip, then the damage zone should be slightly older than the associated slip surface. A consequence of this assumption would be that the width and strain of a damage zone are independent of fault displacement. Empirical data show that this is not the case, even though the fault (slip surface) represents the weakest part of the rock and is therefore prone to reactivation without the creation of more side wall damage. The reason is simply that faults are not perfectly planar structures, nor do they expand within a perfect plane. Faults are irregular at many scales because the rocks that they grow in are both heterogeneous and anisotropic. For example, faults may bend as they meet a different lithologic layer or as they link with other faults. 

The structures in the damage zone form both prior to, during and after the local formation of the slip surface (fault).

If the fault is temporarily or locally planar and smooth, then there may be periods during which displacement accumulates without any deformation of the wall rocks, i.e. without any widening of the damage zone. However, at locations of fault linkage or fault bends, wall damage may also occur during fault growth, which leads to a local widening of the damage zone. Eventually, the fault may find a more planar way through zones of complications, and the damage zone becomes inactive again. Thus, the growth of damage zones may be temporal and local, contributing to the scatter.


The ductile drag zone 

Drag is best defined as any systematic change in the orientation of layers or markers adjacent to a fault in a way that makes it clear that the change deflection is genetically related to the fault. Commonly, the term drag describes zones some meters or tens of meters wide. However, hanging-wall synclines related to normal faults in continental rift basins can extend several hundred meters into the hanging wall. Similarly, large-scale roll overs (reverse drag), up to several kilometres long on the hanging-wall side are associated with large listric faults.

Drag is folding of layers around a fault by means of brittle deformation mechanisms, directly related to the formation and/or growth of the fault.

Drag is seen in layers that are soft enough to deform ductilely in the upper, brittle part of the crust, most commonly in faulted sedimentary sequences. Although drag is commonly limited to a few-meters-wide zone along the fault, it may also be large enough to be imaged on seismic data, which in Drag can form in any tectonic regime. The kinematic requirement is that the angle between the slip vector of the fault and the layering is not too small. Because layering tends to be sub-horizontal in sedimentary rocks, drag is most commonly associated with normal and reverse faults and less commonly developed along strike-slip faults. Folds also develop in sub-horizontal layers along strike slip faults, but these are not drag folds. Thus, we may want to add another characteristic of drag folds:

There are two geometrically different types of drag: normal drag and reverse drag. Normal drag is the shear zone-like geometry where layers flex toward parallelism with the fault. Normal drag involves displacement, so that the total offset is the sum of the ductile normal drag and the discrete fault displacement. Reverse drag is used for the usually larger-scale roll over structures that occur on the hanging-wall side of listric normal faults. In this case the layers are concave in the slip direction. Both normal and reverse drag occur along faults, depending on the local fault geometry. It was originally thought that drag was the result of friction along the fault during fault growth, but the term now includes bending of the layers prior to fault formation. The latter model seems to fit many examples of drag. This model is similar to that of damage zone development: in both cases layers are deformed in the wake of the fault tip. The difference is that drag folding is ductile down to a certain scale, commonly that of a hand sample. The geometry of a drag fold contains information about how it formed. A drag fold in which the layers have the same geometry along the fault, with constant width of drag zone dip isogons running parallel to the fault trace, can be modelled by simple shear. In this case we have a simple shear zone with a central discontinuity. In other cases the drag zone is upward-widening, and a different kinematic model must be applied. A popular model is called trishear. In this model strain is distributed in a triangular or fan-shaped zone of active deformation ahead of the fault tip. This zone moves through the rock as the fault propagates, and no further folding occurs once the fault has cut through the layers. The width of the triangular deformation zone varies from case to case, but in all cases the drag zone widens up section. This model seems to work particularly well in places of reactivated basement faults that grow into overlying sedimentary strata. Many examples of such structures are found in the uplifts on the Colorado Plateau and in the Rocky Mountains foreland in Wyoming and Colorado, where the fold structures are commonly referred to as forced folds. Folds that form ahead of a propagating fault tip are called fault propagation folds. Thus, many drag folds are faulted fault propagation folds. However, drag can also form or become accentuated in the walls of an already existing fault. Just like the damage zone, fault drag can develop due to locking of the fault at fault bends, fault linkage and other complications that can increase the friction along faults. The latter mechanism can take drag to the point where the rotated layer, which typically consists of clay or shale, forms a smear along the fault.

Drag, deformation mechanisms and the damage zone 

Drag can occur by granular flow, particularly in poorly lithified sediments. Granular flow leaves little or no trace of the deformation except for the rotation of layering or modification of sedimentary structures. In consolidated sedimentary rocks grains may start to fracture, and the mechanism becomes distributed cataclastic flow. The mechanisms are the same as those that operate in the different deformation bands discussed in the previous chapter, but the deformation during drag folding is less localized and strain is generally lower. There is, however, a strain gradient toward the fault. Fractures or deformation bands may occur in drag zones. In such cases the density of fractures or deformation bands increases toward the fault. The appearance of mesoscopically mappable fractures or deformation bands indicates that we are in the damage zone. Where drag folds are well developed, the drag zone tends to be wider than the damage zone, although the opposite situation also occurs. Some faults, particularly in metamorphic rocks, show drag-like folding of the layering. A closer examination of many such “drag” folds reveals that they are controlled by plastic deformation mechanisms and are thus shear zones around faults that could have formed in a variety of ways, generally in the zone of brittle–plastic transition. We generally do not consider such plastic fold structures as drag folds, although the similarity can be striking.

Fault growth and seismicity 

Once a fault surface is established it will represent a mechanically weak structure that is likely to fail again during renewed stress build-ups. Faults grow by two mechanisms. The most common one is called stick-slip, where slip accumulates at very sudden seismic slip events, separated by periods of no slip. Stress builds up between the slip events until it exceeds the frictional resistance of the fault. This is the model used to understand earthquakes, where each slip event causes an earthquake whose magnitude is related to the amount of energy released during the stress drop. In terms of strain, this is related to the amount of elastic strain that is released as the fault moves.

The other way for faults to accumulate slip is by stable sliding or a seismic slip. Ideally, displacement accumulates at a constant rate during stable sliding. Some laboratory experiments show that a gradually increasing force is needed for slip to continue. This effect is called slip hardening and is related to damage of the slip surface during deformation. Several factors control whether fault displacement accumulates gradually or by sudden slip events. Rock experiments indicate that stable sliding is more likely when the normal stress across the fault is small, which means that stable sliding is more common in the uppermost part of the brittle crust than deeper down. Low angle faults along over pressured layers in a sedimentary sequence would also be likely to experience stable sliding even at depths of several kilometres because overpressure reduces the effective normal stress across the fault. Lithology is another important factor: porous sediments and sedimentary rocks are more likely to deform by stable sliding than are low-porosity crystalline rocks. In particular, stick-slip is favoured in low-porosity quartz rich siliceous rocks, while clay promotes stable sliding. Clay-bearing in cohesive fault gouge in the fault core has some of the same effect as clay stone: thick and continuous zones of clay gouge promote stable sliding. The fact that gouges (or rather slip surfaces along gouge zones) tend to represent pathways for fluid flow may add to their ability to slide in a stable fashion. Close to the brittle–plastic transition, elevated temperatures introduce plastic deformation mechanisms that also promote stable sliding. Stick-slip deformation is of minor importance in the plastic regime, which for granitic rocks means temperatures above 300 C. In summary, we could say that in the very top of the crust (upper kilometre or two), earthquakes are expected to be rare because of low normal stresses, weak and unconsolidated fault cores (gouge) and, at least in sedimentary basins, weak and porous rocks in general. Below this depth one would expect abundant seismic or stick slip activity until the brittle-plastic transition is reached. This is exactly what earthquake data indicate, and the zone is called the seismogenic zone. Typically, a single fault in the seismogenic zone shows evidence of both stick-slip and stable sliding. While seismic events may be responsible for the majority of total displacement accumulated over time, slow, a seismic “creep” is found to occur between seismic events. There is also a need for small post seismic adjustments that may or may not be seismic. Seismic means sudden energy release and displacement accumulations by means of earthquakes. A seismic means gradual displacement accumulation without the generation of earthquakes. Fault slip and displacement accumulation are commonly discussed in terms of seismicity and seismic slip behaviour. It is important to realize that a single earthquake is unlikely to add more than a few meters of displacement. A quake of magnitude 6.5–6.9 that activates a 15–20 km long fault adds no more than one meter of maximum displacement to a fault. Only the largest earthquakes can generate offsets of 10–15 m. This has a very important implication:
It is worth noting that the accumulation of such displacements would take thousands or millions of years, depending on the local displacement rate. Throw rates for faults can be found by dating sedimentary layers that are offset and measuring their displacements. Average displacement rates of around 1–10 mm/year have been published for major faults in tectonically active areas. Large faults tend to slip along just a limited portion of the total fault surface. The total displacement distribution for a large fault is therefore the sum of displacements contributed by individual slip events (earthquakes). While it seems clear that single slip events produce more or less elliptical displacement contours, the finite displacement distribution from a large number of slip events (earthquakes) is more difficult to predict or understand. The characteristic earthquake model assumes that each slip event is equal to the others in terms of slip distribution and rupture length. However, the location of the displacement maximum is shifted for each slip event. The variable slip model predicts that both the amount of slip and the rupture length vary from event to event, while the uniform slip model considers the slip at a given point to be the same in each slip event (the area varies). We will not go into the details of these models here, but simply state that displacement accumulation results in a displacement maximum near the middle of the fault, gradually tapering off toward the tips.
Credits: Haakon Fossen (Structural Geology)

Accumulation of organic matter


It is well documented that oil accumulations are of organic origin and formed from organic matter in sediments. Methane can be formed inorganically and is found in the atmosphere of several other planets, but inorganic methane from the interior of the earth is likely to be well dispersed and thus not form major gas accumulations in the earth’s crust. The organic matter from which petroleum is derived originated through photosynthesis, i.e. storage of solar energy. Sunlight is continuously transformed into such energy on Earth but only a very small proportion of the solar energy is preserved as organic matter and petroleum. The oil and gas which forms in sedimentary basins each year is thus minute in comparison with the rate of exploitation (production) and consumption. In practice petroleum must therefore be regarded as a non-renewable resource even though some petroleum is being formed all the time. Most of the organic materials which occur in source rocks for petroleum are algae, formed by photosynthesis.The zoo plankton and higher organisms that are also represented grazed the algae and were thus indirectly dependent on photosynthesis too. The energy which we release when burning petroleum is therefore stored solar energy. Since petroleum is derived from organic matter, it is important to understand how and where sediments with a high content of organic matter are deposited. The total production of organic material in the world’s oceans is now 5×1010 tonnes/year. Nutrients for this organic production are supplied by erosion of rocks on land and transported into the ocean. The supply of nutrients is therefore greatest in coastal areas, particularly where sediment-laden rivers discharge into the sea. Plant debris is also supplied directly from the land in coastal areas. Biological production is greatest in the uppermost 20–30 m of the ocean and most of the phytoplankton growth takes place in this zone. In clear water, sunlight penetrates much deeper than in turbid water, but in clear water there is usually little nutrient supply. At about 100–150 m depth, sunlight is too weak for photosynthesis even in very clear water. Phytoplankton provides nutrition for all other marine life in the oceans. Zooplankton feed on phytoplankton and therefore proliferate only where there is vigorous phytoplankton production. Organisms sink after they have died, and may decay so that nutrients are released and recycled at greater depths. Basins with restricted water circulation will preserve more organic matter and produce good source rocks which may mature to generate oil and gas. In polar regions, cold dense water sinks to great depths and flows along the bottom of the deep oceans towards lower latitudes. This is the thermal conveyor belt transporting heat to higher latitudes and it keeps the deep ocean water oxidizing. In areas near the equator where the prevailing winds are from the east the surface water is driven away from the western coast of the continents. This generates a strong up welling of nutrient-rich water from the bottom of the sea which sustains especially high levels of primary organic production. The best examples of this are the coast of Chile and off West Africa. Through photosynthesis, low energy carbon dioxide and water are transformed into high energy carbohydrates (e.g. glucose):

CO2 + H2O → CH2O (organic matter) + O2

The production of organic matter is not limited by carbon dioxide or water, but by nutrient availability. 
Phosphorus (P) and nitrogen (N) are the most important nutrients, though the supply of iron can also be limiting for alga production. It is this process of photosynthesis, which started 4 billion years ago, that has built up an atmosphere rich in oxygen while accumulating reduced carbon in sedimentary rocks as oil, gas and coal. Most of the carbon is nevertheless finely divided within sedimentary rocks, for example shales and limestones, in concentrations too low to generate significant oil and gas. Energy stored by photosynthesis can be used directly by organisms for respiration. This is the opposite process, breaking carbohydrates down into carbon dioxide and water again, so that the organisms gain energy. This occurs in organisms at night when there is no light to drive photosynthesis. Also when we burn hydrocarbons, e.g. while driving a car, energy is obtained by oxidation, again essentially reversing the photosynthesis equation quoted above. Oxidation of 100 g glucose releases 375 kcal of energy. Carbohydrates that are produced but not consumed by respiration can be stored as glucose, cellulose or starch in the cell walls. Photosynthesis is also the biochemical source for the synthesis of lipids and proteins. Proteins are large, complex molecules built up of condensed amino acids (e.g. glycine (H2NCH2−COOH)). 
Dried phytoplankton contains 45–55% carbon, 4.5–9% nitrogen, 0.6–3.3% phosphorus and up to 25% of both silica and carbonate. Planktonic algae are the main contributors to the organic matter which gives rise to petroleum. Among the most important are diatoms, which have amorphous silica (opal A) shells.
Diatoms are most abundant in the higher latitudes and are also found in brackish and fresh water. Blue - green algae (cyanobacteria) which live on the bottom in shallow areas, also contribute to the organic material in sediments. In coastal swamps, and particularly on deltas, we have extensive production of organic matter in the form of plants and trees which may avoid being oxidised by sinking into mud or bog. The residues of these higher land plants may form peat, which with deeper burial may be converted into lignite and bituminous coal. But such deposits are also a potential source of gas and oil. Plant matter, including wood, also floats down rivers and is deposited when it sinks to the bottom, usually in a near shore deltaic environment. When the trees rot they release CO2 and consume as much oxygen as the plant produced during the whole period when it was growing. There is thus no net contribution of oxygen to the atmosphere. This also applies to the bulk of the tropical rainforests. Where trees and plants sink into black mud, preventing them from being oxidised, there is a net contribution of oxygen to the atmosphere and a corresponding reduction of CO2 in the atmosphere. All animal plankton (zooplankton) live on plant plankton, and in turn are eaten by higher organisms in the food chain. At each step in the food chain, which we call a trophic level, the amount of organic matter (the biomass) is reduced to 10%. Ninety percent of the production of organic matter is therefore from algae. This is why algae and to some extent zooplankton account for the bulk of the organic material which can be transformed into oil. Larger animals such as dinosaurs are totally irrelevant as sources of oil. The most important of the zooplankton which provide organic matter for petroleum are:
Radiolaria
Foraminifera
Pteropods
  1. Radiolaria – silica shells, wide distribution, particularly in tropical waters. 
  2. Foraminifera – shells of calcium carbonate. 
  3. Pteropods – pelagic gastropods (snails) with a foot which has been converted into wing-shaped lobes; carbonate shells.
This is the second lowest level within the marine food chain. These zooplanktonic organisms are eaten by crustaceans which themselves are eaten by fish. The total amount of organic matter that can be produced in the ocean is dependent on the nutrient supply from rivers, but river water does not only carry inorganic nutrients. It also contains significant amounts of organic matter, in particular humic acid compounds, lignin and similar substances formed by the breakdown of plant material which are weakly soluble in cold water. When the river water enters the sea, there is precipitation due to the increased pH and lower surface temperature in the ocean. Other plant materials, like waxes and resins, are more chemically resistant to breakdown and are insoluble in water. Such organic particles tend to attach themselves to mineral grains and accompany sediment out into the ocean. Most of the oil reservoirs which have been formed since the Palaeozoic have been uplifted and eroded, and over time vast quantities of oil have flowed (seeped) out onto the land or into the sea. In this sense, oil pollution is a natural process. Only a small proportion of the petroleum that has been formed in source rocks has actually become trapped in a reservoir. One might expect this seepage to have provided a source of recycled petroleum in younger sediments, but petroleum breaks down extremely rapidly when subjected to weathering, oxidising to CO2, and the nutrients (P, N) that were required to form the organic matter are released and may act like a fertilizer. On land, evaporation will remove the lighter components while bacteria will degrade the heavier components. Fossil asphalt lakes consist of heavy substances which neither evaporate nor can be easily broken down by bacteria. In the ocean, the lighter components will dissolve quite rapidly, while the heavier asphalt fraction will sink to the bottom and be degraded and recycled. In uplifted sedimentary basins like the Ventura Basin and the Los Angeles Basin in Southern California there are abundant natural oils seeps both onshore and offshore. On the beaches from Santa Barbara towards Los Angeles there are many natural oil seeps.

Formation of coal, oil and gas


The branch of geology that has the greatest economic importance worldwide is the study of fossil fuels (coal, oil and natural gas): they form by diagenetic processes that alter material made up of the remains of organisms. The places where the original organic material forms can be understood by studying depositional processes, but the formation of coal from plant material and the migration of volatile hydrocarbons as oil and gas require an understanding of the diagenetic history of the sedimentary rocks where they are found.

Coal-forming environments


Vegetation on the land surface is usually broken down either by grazing animals or by microbial activity. Preservation of the plant material is only likely if the availability of oxygen is restricted, as this will slow down microbial decomposition and allow the formation of peat, which is material produced by the decay of land vegetation. In areas of standing or slowly flowing water conditions can become anaerobic if the oxygen dissolved in the water is used up as part of the decay process. These waterlogged areas of accumulation of organic material are called mires, and are the principal sites for the formation of thick layers of peat. Mires can be divided into two types: areas where most of the input of water is from rainfall are known as ombotrophic mires or bogs; places where there is a through-flow of groundwater are called rheotrophic mires or swamps. In addition there are also rheotrophic mires that have an input of clastic sediment, and these are referred to as marshes, or salt marshes if the water input is saline.

The significance of these different settings for peat formation is that these environmental factors have a strong influence on the quality and economic potential of a coal that might subsequently be formed. Bogs tend to have little clastic input, so the peat (and hence coal) is almost pure plant material: the peat can be many metres thick, but is usually of limited lateral extent. Swamp environments can be more extensive, but the through-flowing water may bring in clay, silt and sand particles that make the coal impure (it will have a high ash content). Also, if the water is saline, it will contain sulphates and these lead to the formation of sulphides (typically iron pyrite) in the coal and give the deposit a high sulphur content: this is not desirable because it results in sulphur dioxide emissions when the coal is burnt. The ash and sulphur content are the two factors that are considered when assessing the coal grade, as the lower they are, the higher the grade. A wet environment is required to form a mire and therefore a peat, so environments of their formation tend to be concentrated in the wetter climatic belts around the Equator and in temperate, higher latitudes. In warmer climates plant productivity is greater, but the microbial activity that breaks down tissue is also more efficient. Both plant growth and microbial breakdown processes are slower in cooler environments, but nevertheless the fastest rates of peat accumulation (over 2mm yr 1) are from tropical environments and are ten times the rate of peat accumulation in cooler climes. Coals that originate as peat deposits are known as humic coals, but not all coals have this origin. Sapropelic coals are deposits of aquatic algae that accumulate in the bottoms of lakes and although they are less common, they are significant because they can be source rocks for oil: humic coals do not yield oil, but can be the origins of natural gas.

Formation of coal from peat

The first stage of peat formation is the aerobic, biochemical breakdown of plant tissue at the surface that produces a brownish mass of material. This initially formed peat is used as a fuel in places, but has a low calorific value. The calorific value is increased as the peat is buried under hundreds of metres of other sediment and subjected to an increase in temperature and pressure. Temperature is in fact the more important factor, and as this increases with depth (the geothermal gradient) the peat goes through a series of changes. Volatile compounds such as carbon dioxide and methane are expelled, and the water content is also reduced as the peat goes through a series of geochemical changes. As oxygen, hydrogen and nitrogen are lost, the proportion of carbon present increases from 60% to over 90%, and hence the calorific value of the coal increases. Differences in the degree to which the original peat has been coalified are described in terms of coal rank. Transitional between peat and true coal is lignite or brown coal, which is exploited as an energy source in places. Going on through the series, low-rank coal is referred to as sub-bituminous coal, middle rank is bituminous and the highest rank coals are known as anthracite. In the process of these reactions, the original layer of peat is reduced considerably in thickness and a bed of bituminous coal may be only a tenth of the thickness of the original layer of peat.

Formation of oil and gas


Naturally occurring oil and gas are principally made up of hydrocarbons, compounds of carbon and hydrogen: petroleum is an alternative collective term for these materials. The hydrocarbon compounds originate from organic matter that has accumulated within sedimentary rocks and are transformed into petroleum by the processes of hydrocarbon maturation. This takes place in a series of stages dependent upon both temperature and time. The first stage is biochemical degradation of proteins and carbohydrates in organic matter by processes such as bacterial oxidation and fermentation. This eogenesis eliminates oxygen from kerogen, the solid part of the organic matter that is insoluble in organic solvents. 
Three main types of kerogen are recognised: 
  • Type I is derived from planktonic algae and amorphous organic material and is the most important in terms of generating oil.
  • Type II consists of mixed marine and continental organic material (algae, spores, cuticles) which forms gas and waxy oils.
  • Type III originates from terrestrial woody matter and is a source of gas only. 
Eogenesis occurs at temperatures of up to 408 C and at up to depths of just over 1000 m. At burial depths of between about 1000 and 4000 m and at temperatures of between 408 C and 1508 C, the phase of diagenesis known as catagenesis further transforms the kerogen. This stage of thermal maturation is also known as the ‘oil window’ because liquid petroleum forms from Type I kerogen under these conditions. With increasing temperature the proportion of gas generated increases. Generation of oil by organic maturation of kerogen is a process that requires millions of years, during which time the strata containing the organic matter must remain within the oil window of depth and temperature. At higher temperatures and burial depths only methane is produced from all kerogen types, a stage known as metagenesis. Formation of oil, which is made up of relatively long-chain hydrocarbons that are liquid at surface temperatures, from sedimentary organic matter requires a particular set of conditions. First, the organic matter must include the remains of planktonic algae that will form Type I kerogen: this material normally accumulates in anaerobic conditions in anoxic marine environments and in lakes. Second, the organic material must be buried in order that catagenesis can generate liquid hydrocarbons within the correct temperature window: if buried too far too quickly only methane gas will be formed. The third factor is time, because the kerogen source rock has to lie within the oil window for millions of years to generate significant quantities of petroleum. Gas consisting of short-chain hydrocarbons, principally methane, is formed from Type III kerogen and at higher maturation temperatures. Burial of coal also generates natural gas (principally methane) and no oil. The methane generated from coal may become stored in fractures in the coal seam as coal bed methane, which is a hazard in underground coal mining, but can also be exploited economically.


Oil and gas reservoirs

The hydrocarbons generated from kerogen are compounds that have a lower density than the formation water present in most sedimentary successions. They are also immiscible with water and droplets of oil or bubbles of gas tend to move upwards through the pile of sedimentary rocks due to their buoyancy. This hydrocarbon migration proceeds through any permeable rock until the oil or gas reaches an impermeable barrier.

Hydrocarbon traps

Oil and gas become trapped in the subsurface where there is a barrier formed by impermeable rocks, such as well-cemented lithologies, mudrock and evaporite beds. These impermeable lithologies are known as cap rocks. The hydrocarbons will find their way around the cap-rock barrier unless there is some form of hydrocarbon trap that prevents further upward migration. Structural traps are formed by folds, such as anticlines, especially if they are domeshaped in three dimensions, and by faults that seal a porous reservoir rock against an impermeable unit. Other traps are stratigraphic traps, formed beneath unconformities and in places where the reservoir rock pinches out laterally: porous rocks such as limestone reefs that pass laterally into finer grained deposits and where sand bodies are laterally limited and enclosed by mudrocks are examples of stratigraphic traps. The size and shape of the trap determines the volume of oil and/or gas that is contained by the structure, and hence is an important factor in assessing the economics of a potential oil field. In the absence of traps and caps the hydrocarbon reaches the surface and leaks to the atmosphere. Partial release of hydrocarbons from the subsurface as oil seeps and gas seeps can be important indicators of the presence of hydrocarbons.

Reservoir rocks

Almost all oil and gas accumulations occur underground within the pore spaces of beds of sedimentary rocks. In a few rare cases there are accumulations of hydrocarbons in subterranean caverns formed by dissolution of limestone, but the vast majority of reserves are known hosted between grains in sandstones or within the structures of limestones. For a sedimentary rock to be a suitable reservoir unit, it must be both porous and permeable. Porosity is presented as a percentage of the rock volume. Permeability is expressed in darcy units, with a value of 1 darcy representing a very good permeability for a hydrocarbon reservoir. Some of the best reservoir facies are beds of wellsorted sands deposited in sandy deserts and shallow seas, because these contain a high primary porosity. For similar reasons oolitic grainstones can be good reservoirs, and boundstones formed in reefs have a lot of void spaces within the original structure. There are examples of hydrocarbon reservoirs in deposits of many other environments, including rivers, deltas and submarine fans. Limestones may also have important secondary porosity due to dissolution and diagenetic changes. The reservoir quality of a rock is reduced by two main factors. First, the presence of mud reduces both porosity and permeability because clay minerals fill the spaces between grains and block the throats between them. Second, cementation reduces porosity and permeability by crystallising
minerals in the pore spaces, sometimes to the extent of reducing the porosity to zero.

Economic oil and gas accumulations


Exploration for economic reserves of hydrocarbons requires knowledge of the depositional history of an area to determine whether suitable source rocks are likely to have formed and if there are any suitable reservoir and cap lithologies in the overlying succession. This analysis of the sedimentology is an essential part of oil and gas exploration. Knowledge of postdepositional events is also important to provide an assessment of the thermal and burial history that controls the generation of hydrocarbons.

Carbonate diagenesis


Cements in carbonate rocks are mainly made up of calcium carbonate derived from the host sediment. Lithification of aggregates of carbonate material can occur as eogenetic cementation contemporaneously with deposition in any settings where there is either a lot of seawater being circulated through the sediment or where sedimentation rates are low. Beach-rock may be formed of carbonate debris deposited on the beach that is cemented by calcium carbonate from seawater washing through it in the intertidal to supratidal zone. In warm tropical shallow marine environments the seawater is often saturated with respect to calcium carbonate and cementation can take place on the sea floor forming a hardground or firmground if sedimentation rates are low. The cementation can be localised and related to microbial activity within the sediment, for example, it may be associated with burrows. Colder seawater is undersaturated with calcium carbonate and dissolution of carbonate material can occur. In non-marine environments calcite cementation occurs in both the vadose zone (above the water table) and in the phreatic zone (below the water table). In the vadose environment, for example in caves and in streams, the precipitation of the calcite to form these cements is due to the degassing of water: the resulting deposits are stalactites and stalagmites in caves (or speleothems, the general term for cave deposits), and travertine deposited from surface waters in places such as waterfalls. In soils calcite precipitation forms cements as rhizoliths and calcrete as a result of the evaporation of groundwater and the addition of calcium carbonate as wind-blown dust. Syn-sedimentary precipitation of siderite can occur where there is mixing of seawater and fresh water under reducing conditions: this can happen in coastal marshes. Burial stage (mesogenetic) cementation by calcite largely involves carbonate derived from the dissolution of carbonate grains. These cements are low magnesium calcite and are in the form of bladed crystals that grow out from the grain margins into the pore spaces or as overgrowths, particularly on crystalline fragments of echinoids and crinoids, from which they may develop a poikilotopic fabric.

Compaction effects in limestones: stylolites and bedding planes


Calcite undergoes pressure dissolution under the pressure of a few hundred metres of overburden, forming solution surfaces within the rock known as stylolites. At a small scale (millimetres to centimetres), stylolites are usually highly irregular solution surfaces that are picked out by concentrations of clay, iron oxides or other insoluble components of the rock. Where a stylolite cuts through a fossil it may be possible to determine the amount of calcium carbonate that has been dissolved at the surface. They normally form horizontally in response to overburden pressure, but can also form in response to tectonic pressures at high angles to the bedding. At a larger scale, horizontal pressure solution surfaces within a limestone succession create apparent bedding surfaces that may be very sharply defined by the higher concentration of clay along the surface, but do not necessarily represent a break in sedimentation. This apparent bedding, which is diagenetic in origin, may be more sharply defined in outcrop than true bedding surfaces representing primary changes and breaks in deposition. Pressure solution can result in the removal of large amounts of calcium carbonate and concentrate the clay component of an impure, muddy limestone to leave nodules of limestone in a wavy-bedded mudstone.

Dolomitisation

Dolomite is a calcium magnesium carbonate (CaMg (CO3)2) mineral that is found in carbonate sedimentary rocks of all ages and when the mineral forms more than 75% of the rock it is called a dolostone, although the term dolomite is also often used for the rock as well as for the mineral. The mineral is relatively uncommon in modern depositional environments: it is known to occur in small quantities in arid coastal settings, where its formation may be related to microbial activity. However, these modern examples do not provide an explanation for the thick successions of dolostone that are known from the stratigraphic record and most dolomite is believed to form diagenetically, a process known as dolomitisation. Many dolostones in the stratigraphic record contain fossils that indicate normal marine environments of deposition and show replacement fabrics where material that was clearly originally made up of calcite or aragonite has been wholly or partially replaced by dolomite. The mechanism of formation of dolomite by reaction of seawater and pore water with calcite and aragonite has been the subject of much debate and a number of different models have been proposed, all of which may be applicable in different circumstances. All models have certain things in common: the original rock must be limestone, the water that reacts with it must be marine, or pore water derived from seawater, and there must be abundant, long-term supply of those waters for large-scale dolomitisation to take place. The process of dolomitisation also seems to be favoured by elevated temperatures and by either enhanced or reduced salinities compared with seawater. The mixing-zone model for dolomitisation proposes that where fresh water, which is under-saturated with respect to calcite but over-saturated with respect to dolomite, mixes with marine waters then dolomitisation would occur. Although there may be a theoretical basis for this model, the process has not been observed in any of the many coastal regions around the world where conditions should be favourable. Arid coastal regions where concentrated brines promote dolomitisation have been suggested in the reflux model, but although this may result in formation of dolomite in the sediment within 1 or 2m of the surface, this mechanism does not seem to be capable of generating large volumes of dolomite. It seems more likely that large-scale dolomitisation occurs at some point after burial and hence a number of burial models or seawater models have been proposed. Thick successions of platform limestone can be transformed wholly or partly into dolostone if seawater, or pore-water brines that originated as seawater, can be made to pass through the rock in large quantities for long periods of time. Compaction has been suggested as a potential driving force for fluid transport, but seems unlikely to be capable of producing the quantities of fluids required. Thermally driven circulation, either by a geothermal heat source or by temperature differences between the interior of a platform and seawater, is the most likely candidate for generating long-term flow of the large quantities of fluid required. Topography can also provide a means of forcing water flow through rocks, but although meteoric waters (i.e. derived from rainfall) may provide an abundant flux of fluids, they rarely contain sufficient magnesium to promote dolomitisation. A reversal of the process that causes dolomitisation in association with evaporites can result in dolomite being replaced by calcite. This dedolomitisation occurs where beds of gypsum are dissolved enriching groundwaters in calcium sulphate. The sulphate-rich waters passing through dolostone result in the replacement of dolomite by calcite.

Diagenesis and carbonate petrography

Most carbonate sediments become lithified during diagenesis and can readily be cut to make thinsections: injection of blue resin into the pore spaces is nevertheless commonly carried out in order to make any voids within the rock visible. The blue-dyed resin shows up porosity in carbonate rocks that can either be between the grains (interparticle porosity) or within grains as intraparticle porosity, usually chambers within fossils such as foraminifers, cephalopods and gastropods. Distinguishing between cement and matrix and even between grains and cement is not always straightforward in carbonate rocks because all have the same, or very similar, mineralogy: the morphology of the carbonate material therefore provides most of the important clues as to its origin. Grains within limestone that are biogenic in origin usually have distinctive shapes that reflect the structure of the organism, even if they are only small fragments. Similarly, ooids and peloids are easily recognised in thin-sections. Lithic clasts of limestone and intraclasts have more variable shapes and structures and, because they are in fact pieces of rock, may include areas of cement: distinguishing between the cement within intraclasts and the later cement of the whole rock can sometimes be difficult. Peloids are typically made up of carbonate mud, and must therefore be distinguished from a muddy matrix on the basis of their shape.

Neomorphism

Carbonate mud is the main constituent of carbonate mudstones and wackestones, and can occur as a
matrix in packstones, grainstones and boundstones. Individual grains are clay-sized and therefore cannot be individually seen with a petrographic microscope. Neomorphism (replacement by recystallisation) of carbonate mud to form microcrystalline sparry calcite commonly occurs, and as this results in an increase in crystal size, it may then be possible to see the crystalline form under the microscope: although it may be difficult to resolve individual crystals, the microspar appears as a mass of fine crystalline materials showing different birefringence colours under crossed polars. The birefringence colours of carbonates are high-order pink and green, which may appear to merge into a pale brown if the individual crystals are very small or the magnification is low. Shelly or skeletal material composed of aragonite undergoes replacement by calcite, either by the solution of the aragonite to create a void later filled by calcite, or by a direct mineral replacement. In the former case the internal structure is completely lost, but where the aragonite is transformed into calcite some relics of the original internal structure may be retained, seen as inclusions of organic matter. The neomorphic calcite crystals are larger than the original aragonite crystals, are often slightly brown due to the presence of the organic material and occur as an irregular mosaic occupying the external form of the skeletal material.

Carbonate cements

Cementation ofcarbonate sediment to form a limestone can involve a number of stages of cement formation. The form of eogenetic cements is determined by the position of the sediment relative to the groundwater level. In the phreatic zone, in which all the pore spaces are filled with water, the first stage is the formation of a thin fringe of calcite or aragonite growing perpendicular to the grain boundary out into the pore space: these crystals form a thin layer of approximately equal thickness over the grains and are hence known as isopachous cement. Above the water level, in the intertidal and supratidal zones, the sediment is in the vadose zone and is only periodically saturated with water: the cement forms only where grains are close together within water held by surface tension to form a meniscus, and hence they are called meniscus cements. A bladed, fibrous or acicular morphology is characteristic of these early cements, with the long axes of the crystals oriented perpendicular to the grain edge. Very fine-grained, micritic, cements can also form at this stage. Recrystallisation of these eogenetic cements commonly occurs because if their original mineralogy was either aragonite or high-magnesium calcite they undergo change to low magnesium calcite through time. Many limestones have a cement of sparry calcite that fills in any pore space that is not occupied by an early cement. The interlocking crystals of clear calcite are believed to form during burial diagenesis (mesogenetic cement) from pore waters rich in calcium carbonate. If there are fragments of echinoids or crinoids present in the sediment the sparry cement precipitates as a syntaxial overgrowth and can form poikilotopic fabric as the cement crystals completely envelop a number of grains. The source of the calcium carbonate for these sparry cements may be from the dissolution of aragonite from shelly material or it may come from pressure solution at grain contacts and along stylolites.

Dolomite


Most dolomite occurring in sedimentary rocks is diagenetic in origin, occurring as a replacement of calcite. Although the optical properties of calcite and dolomite are very similar, dolomite commonly occurs as distinctive, small rhomb-shaped crystals that replace the original calcite fabric. Staining the thin section with Alizarin Red-S provides confirmation that the mineral is dolomite (which does not stain pink) as opposed to calcite (which does). Extensive dolomitisation may completely obliterate the primary fabric of the limestone, resulting in a rock that appears in thin-section as a mass of rhombic crystals. The transformation of calcite into dolomite results in a decrease in mineral volume and consequently an increase in porosity.