Sunday, 5 April 2015

Amphibolite

What is Amphibolite?

Amphibolite is a non foliated metamorphic rock that is mainly composed of mineral amphibole and plagioclase feldspar with little or no quartz. The amphibole are usually the member of the hornblende group. It can also contains other metamorphic minerals such as biotite, epidote, garnet, wollastonite, andalusite, staurolite, kyanite and sillimanite. It is typically dark coloured and heavy with a weak foliated or schistose structure. The small flakes of white and black minerals in the rock often give it a salt and pepper appearance. 
Amphibolite is a metamorphic rock that contains amphibole, especially the species hornblende and actinolite, as well as plagioclase. A holocrystalline plutonic igneous rock composed primarily of hornblende amphibole is called a hornblendite, which is usually a crystal cumulate rock. Rocks with >90% amphiboles which have a feldspar ground-mass may be a lamprophyre.
Amphibolite is a grouping of rocks composed mainly of amphibole and plagioclase feldspars, with little or no quartz. It is typically dark-colored and heavy, with a weakly foliated or schistose (flaky) structure. The small flakes of black and white in the rock often give it a salt-and-pepper appearance.
Amphibolites need not be derived from metamorphosed mafic rocks. Because metamorphism creates minerals based entirely upon the chemistry of the protolith, certain 'dirty marls' and volcanic sediments may actually metamorphose to an amphibolite assemblage. Deposits containing dolomite and siderite also readily yield amphibolites (tremolite-schists, grunerite-schists, and others) especially where there has been a certain amount of contact metamorphism by adjacent granitic masses. Metamorphosed basalts create ortho-amphibolites and other chemically appropriate lithologies create para-amphibolites.
Tremolite, while it is a metamorphic amphibole, is derived most usually from highly metamorphosed ultramafic rocks, and thus tremolite-talc schists are not generally considered as 'amphibolites'.

How amphibolite forms?

Amphibolite is a rock associated with the convergent plate boundaries where heat and pressure cause regional metamorphism of mafic igneous rocks such as basalt and gabbro or from the clay rich sedimentary rocks that can be either marl or greywacke. The metamorphism sometimes also flattens and elongates the mineral grains which produces schistocity in the rock.

Protoliths forming amphibolite

Amphibolites need not be derived from metamorphosed mafic rocks. Because metamorphism creates minerals based entirely upon the chemistry of the protolith, Certain 'dirty marls' and volcanic sediments may actually metamorphose to an amphibolite assemblage. Deposits containing dolomite and siderite also readily yield amphibolites especially where there has been a certain amount of contact metamorphism by adjacent granitic masses. Metamorphosed basalts create ortho-amphibolites and other chemically appropriate lithologies create para-amphibolites.

Ortho-amphibolites vs. para-amphibolites

Metamorphic rocks composed primarily of amphibole, albite, with subordinate epidote, zoisite, chlorite, quartz, sphene, and accessory leucoxene, ilmenite and magnetite which have a protolith of an igneous rock are known as Orthoamphibolites.
Para-amphibolites will generally have the same equilibrium mineral assemblage as orthoamphibolites, with more biotite, and may include more quartz, albite, and depending on the protolith, more calcite/aragonite and wollastonite.
Often the easiest way to determine the true nature of an amphibolite is to inspect its field relationships; especially whether it is inter-fingered with other sediments, especially greywackes and other poorly sorted sediments. If the amphibolite appears to transgress apparent protolith bedding surfaces it is an ortho-amphibolite, as this suggests it was a dyke. Picking a sill and thin metamorphosed lava flows may be more troublesome.
Thereafter, whole rock geochemistry will suitably identify ortho- from para-amphibolites.
The word metabasalt was thus coined, largely to avoid the confusion between ortho-amphibolites and para-amphibolites. While not a true metamorphic rock name, as it infers an origin, it is a useful term.

Amphibolite facies

Amphibolites define a particular set of temperature and pressure conditions known as the amphibolite facies. However, caution must be applied here before embarking on metamorphic mapping based on amphibolites alone.
Firstly, for an (ortho) amphibolite to be classed as a metamorphic amphibolite, it must be certain that the amphibole in the rock is a prograde metamorphic product, and not a retrograde metamorphic product. For instance, actinolite amphibole is a common product of retrograde metamorphism of basalts at (upper) greenschist facies conditions. Often, this will take on the crystal form and habit of the original protolith assemblage; actinolite pseudomorphically replacing pyroxene is an indication that the amphibolite may not represent a peak metamorphic grade in the amphibolite facies. Actinolite schists are often the result of hydrothermal alteration or metasomatism, and thus may not, necessarily, be a good indicator of metamorphic conditions when taken in isolation.
Secondly, the microstructure and crystal size of the rock must be appropriate. Amphibolite facies conditions are experienced at temperatures in excess of 500 °C and pressures less than 1.2 GPa, well within the ductile deformation field. Gneissic texture may occur nearby, if not then mylonite zones, foliations and ductile behaviour, including stretching lineations may occur.
While it is not impossible to have remnant protolith mineralogy, this is rare. More common is to find phenocrysts of pyroxene, olivine, plagioclase and even magmatic amphibole such as pargasite rhombohedra, pseudomorphed by hornblende amphibole. Original magmatic textures, especially crude magmatic layering in layered intrusions, is often preserved.
Amphibolite facies equilibrium mineral assemblages of various protolith rock types consist of:
  • Basalt ortho-amphibolite; hornblende/actinolite +/- albite +/- biotite +/- quartz +/- accessories; often remnant greenschist facies assemblages including, notably, chlorite
  • High-magnesia basalts; as ortho-amphibolite, but may contain anthophyllite, a Mg-rich amphibole
  • Ultramafic rocks; tremolite, asbestiform amphibole, talc, pyroxene, wollastonite, prograde metamorphic olivine (rarely)
  • Sedimentary para-amphibolite; hornblende/actinolite +/- albite +/- biotite +/- quartz +/- garnet (calcite +/- wollastonite)
  • Pelites; quartz, orthoclase +/- albite, +/- biotite +/- actinolite +/- garnet +/- staurolite +/- sillimanite
Amphibolite facies is usually a product of Barrovian Facies Sequence or advanced Abukuma Facies Sequence metamorphic trajectories. Amphibolite facies is a result of continuing burial and thermal heating after greenschist facies is exceeded.
Further burial and metamorphic compression (but little extra heat) will lead to eclogite facies metamorphism; with more advanced heating the majority of rocks begin melting in excess of 650 to 700 °C in the presence of water. In dry rocks, however, additional heat (and burial) may result in granulite facies conditions.

Uralite

Uralites are particular hydrothermally altered pyroxenites; during autogenic hydrothermal circulation their primary mineralogy of pyroxene and plagioclase, etc. has altered to actinolite and saussurite (albite + epidote). The texture is distinctive, the pyroxene altered to fuzzy, radially arranged actinolite pseudomorphically after pyroxene, and saussuritised plagioclase.

Epidiorite

The archaic term epidiorite is sometimes used to refer to a metamorphosed ortho-amphibolite with a protolith of diorite, gabbro or other mafic intrusive rock. In epidiorite the original clinopyroxene (most often augite) has been replaced by the fibrous amphibole uralite.

Uses of amphibolite

Amphibolite is harder than limestone and heavier than granite so for this reason amphibolite is quarried and crushed for use as an aggregate in highway construction and as a ballast stone in railroad construction. It is also used as a dimension stone after cutting into specific size and shape. Higher quality of amphibolite is quarried for use as an architectural purposes and as a flooring tiles, facing stone on building exterior and panels indoors.

1 comment:

  1. i appreciate the way you bring out your points and the explanations.
    thank you

    ReplyDelete